This study investigates the combined effect of anodic pretreatment and varying auxiliary formulations
on the dyeing performance of cotton fabric using a natural dye extracted from Butea monosperma
flowers. While past studies have examined the role of mordants and pH modifiers in natural dyeing,
limited attention has been given to how auxiliary systems interact with electrochemically modified fabrics
to influence colour yield and fastness performance. This research addresses that gap by evaluating how
anodically pretreated cotton responds to common dyeing auxiliaries—sodium chloride (NaCl), potassium
aluminium sulfate (alum), sodium carbonate (Na2CO3), and calcium oxide (CaO)—in terms of shade
development, chromatic richness, and durability.
Using the CIE Lab colour system, significant colour variations were observed across all treated
specimens (2–7) compared to the salt-only control (specimen 1). ∆E values ranged from 12.49 to 19.95,
with the highest chromatic shift seen in the NaCl + alum sample, which produced a vivid orange hue
with enhanced redness and yellowness. Combinations of alum and alkalis yielded deeper, more saturated
shades, while alkali-only formulations produced earthier tones with moderate lightness. These outcomes
highlight the synergistic effect of anodic surface activation and auxiliary chemistry on improving dye-fibre
interactions.
Fastness tests, conducted according to ISO 105-C10 and ISO 105-X12 standards, revealed moderate
washing durability (colour change ratings of 3 to 4) and good rubbing fastness (ratings up to 4).
Specimens treated with mordants and alkalis generally exhibited improved fixation and reduced staining,
whereas anodic treatment enhanced surface adhesion of the dye.
This study demonstrates a promising, low-impact approach to improving natural dye uptake and
fastness on cotton fabric by integrating anodic pretreatment with accessible auxiliary systems. The
findings support the development of sustainable, decentralised dyeing processes using locally available
plant waste, with particular relevance for rural craft and textile communities seeking eco-friendly
alternatives to synthetic dyes