Piyanut Jingjit, Yanisa Komonsirichok
This study evaluates the dyeing performance of cotton fabric with a natural dye extracted from the heartwood of Senna siamea, focusing on the e®ects of anodic electrochemical pretreatment combined with varying concentrations of two mordants: potassium aluminium sulfate (alum) and calcium hydroxide. Sodium chloride (10 g/L) was maintained as the auxiliary in all dye baths, while mordant concentrations ranged from 0 to 20 g/L for both alum and calcium hydroxide.
Colourimetric analysis (CIE Lab*) revealed that alum treatment generally lightened the fabric and decreased colour saturation, with ¢E values reaching 13.11 at 20 g/L, indicating a shift toward washed- out shades. In contrast, calcium hydroxide enhanced fabric brightness and signi¯cantly increased yellow chroma, producing warmer and more vibrant hues, particularly at 10 g/L, which was visually the lightest and showed the greatest colour di®erence (¢E = 14.32).
Washing fastness (ISO 105-C10) remained consistently good (ratings 3-4/5) across all mordant types and concentrations. Rubbing fastness (ISO 105-X12) improved with increasing mordant concentration, especially for alum at 15-20 g/L and calcium hydroxide at 10 g/L, with wet rubbing ratings improving from 2/3 to 3/4.
These results highlight the distinct in°uences of alum and calcium hydroxide on colour development and durability, o®ering practical insights for optimising natural dyeing with Senna siamea extract. The study promotes accessible, eco-friendly dyeing techniques suitable for rural artisans, enhancing traditional textile quality and supporting sustainable production.